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The effect of the acidifying group on the regioselectivity of the base-induced ring opening of hetero-oxabicyclic [3. Amphoteric character of 2-vinyloxiranes: A new route to the enantioselective synthesis of cycloheptenols.

Regioselective palladium-catalyzed hydrostannylation of unsymmetrical oxabicyclic alkenes Lautens, M; Klute, W Angew. Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene: Scope of the nickel catalyzed asymmetric reductive ring opening reaction.

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Organoselenium-Catalyzed Mild Dehydration of Aldoximes: Friedman and Mark Lautens Synthesis48 Pd 0 -Catalyzed Carboiodination: Franziska Schoenebeck and Prof. Synthesis of 1,2,3-triazole-fused heterocycles via Pd-catalyzed cyclization of 5-iodotriazoles Jacqueline M. An expedient route for the stereoselective construction of bridged polyheterocyclic ring systems using the tandem ”pincer” Diels-Alder reaction Lautens, M; Fillion, E J. Newman, Mark Lautens, and K. Mild procedure for the catalytic bis stannylation of alkynes dd hexaalkylditins Mancuso, J; Lautens, M Org.


Formation of homoallyl stannanes via palladium-catalyzed stannylative cyclization of enynes Lautens, M; Mancuso, J Org. Enantioselective synthesis of chiral 1,2-diamines by the catalytic ring opening of azabenzonorbornadienes: Burton, Ivan Franzoni, David A.

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Use of 1146 sterically demanding Lewis acid to direct ring expansion of monoactivated methylenecyclopropanes Taillier, C; Bethuel, Y; Lautens, M Tetrahedron63 Preparing substituted azaindole compound, to e. A new route to fused aromatic compounds by using a palladium-catalyzed alkylation – Alkenylation sequence Lautens, M; Piguel, S Angew. Arrowsmith, Matthieu Schapira J.

Celebrating Canadian Chemistry Prof. Total synthesis of – – alpha -kainic acid via a diastereoselective methylenecyclopropane ring expansion Scott, ME; Lautens, M Org. A cycloaddition-fragmentation-cyclization sequence to diquinanes and ds Lautens, M; Blackwell, J Synthesis Origin of Regioselectivity David I.

Exploiting Distal Reactivity of Coumarins: Synthetic studies of the formation of oxazoles and isoxazoles from N-acetoacetyl derivatives: Bryan and Mark Lautens Org. Hashmi, and Mark Lautens Org. Marchese, Mark Lautens Org.

Chemodivergence in enantioselective desymmetrization of diazabicycles: Allylic Substitution Reactions Paquin, J.

Preparation of 2-substituted indole compound, useful for the synthesis of e. Palladium catalyzed hydrostannation-cyclization of 1,6-diynes.


Malik, Mark Lautens Top. Diastereoselective formation of indanes from arylboronate esters catalyzed by rhodium I in aqueous media Lautens, M; Mancuso, J Org.

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Lautens, M; Rovis, T Tetrahedron55 Addition of bifunctional organoboron reagents to strained alkenes. Synthesis and reactions of 1,2-disubstituted methylenecyclopropanes prepared leo intramolecular cyclopropanation of allenic diazoacetates.

Base-induced ring opening of aza- and thiaoxa[3.

Rhodium-catalyzed ring opening of vinyl epoxides with alcohols and aromatic amines Fagnou, K; Lautens, M Org.

Exploring the reactivity of dioxacyclic compounds as a route to polysubstituted decalins and fused polycycles Lautens, M; Fillion, E J.

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New hydronaphthalene compounds useful for preparing active pharmaceutical ingredients e. Chapman and Mark Lautens J. Supplement to Comprehensive Asymmetric Catalysis Synthesis of Benzo-Fused [2. Loh, Matthias Schmid, Dr. Activation and stabilization of aldimines by an ortho-trifluoromethyl substituent in direct vinylogous Mannich-type reactions Lautens, M; Tayama, E; Nguyen, D Tetrahedron Lett.